【Device Papers】Low-Voltage Gallium Oxide Memristor with Enhanced Cyclic Endurance, Stability, and Memory Window

      Researchers from the Iowa State University have published a dissertation titled "Low-Voltage Gallium Oxide Memristor with Enhanced Cyclic Endurance, Stability, and Memory Window" in ACS Applied Electronic Materials.

Abstract

      We present an Al/Cu/GaO_x/Au memristor that combines low-voltage operation (set and reset voltages of 0.48 and −0.3 V, respectively), high cyclic endurance (>13,987 cycles), a large memory window (∼4900), and stable multilevel resistance states. These outstanding properties are achieved by leveraging the synergistic interaction between a Cu-based electrochemical metallization mechanism and a GaO_x intermediate layer. Comparative studies and atomistic simulations reveal that the low energy barrier for Cu diffusion into GaO_x is pivotal in enhancing device performance, enabling superior functionality compared to previously reported GaO_x-based memristors. This memristor supports reliable multilevel resistance programming via compliance current modulation and voltage-controlled filament rupture. Furthermore, its exceptional endurance, among the highest reported for GaO_x memristors, was validated through rigorous current–voltage cycling tests and voltage pulse measurements. This work establishes the Al/Cu/GaO_x/Au memristor as a promising configuration for advancing nonvolatile memory technologies, offering significant potential for high-performance, low-power storage, and neuromorphic computing solutions.

DOI：

https://doi.org/10.1021/acsaelm.4c02238