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【International Papers】Non-equilibrium methods for synthesis and modification of gallium oxide

日期:2023-08-04阅读:175

      A research team  from the Lobachevsky University and Тomsk State University,etc. have published a dissertation titled "Non-equilibrium methods for synthesis and modification of gallium oxide" in the scientific journal “ResearchGate”.

Abstract

      Synthesis and modification of  gallium  oxide  as a  wide-bandgap semiconductor  is a topical task in the fields of power  electronics,  UV  detectors, gas sensors, telecommunication. In the present work, the Ga2O3 films deposited on sapphire substrates by magnetron sputtering have been  studied. The  influence of  deposition parameters  and subsequent  annealing  on  the structure and optical properties of the synthesized films is analyzed. Ion doping of magnetron-deposited films with silicon is carried out by the ion implantation method.  It  is  shown by the Raman  scattering  and  optical  transmission  spectroscopy  that  ion  irradiation  leads  to  the disordering of the crystal structure, but subsequent annealing results in a partial recovery of the structure.  Hall-effect  measurements  for  irradiated  and  then annealed  films  do not  reveal  the formation of a conducting layer. Apparently, this is due to the fact that the main contribution to the resistance is made by grain boundaries in the magnetron-deposited films.

Figure 1. Dependence of Raman spectra on annealing temperature of Ga2O3 magnetron films (a), working pressure, and RF power during the deposition of these films (b).

Figure 2. Raman spectra for magnetron-deposited Ga2O3 films on sapphire irradiated with silicon ions and subsequently annealed. FA means “furnace annealing”. For clarity, the data only for one ion dose are shown.

Paper Link:https://www.researchgate.net/publication/357034831_Non-equilibrium_methods_for_synthesis_and_modification_of_gallium_oxide